I have been trying to find information on this for a while. Once my fiancee (by that time my wife) has adjusted her status and becomes a permanent resident, where can she travel? I have looked every where for a list of countries that do not limit entry to US citizens, but no luck. I am confused because she will still be carrying her South African passport( right?), but she will have a Green Card. Does the Green Card make it possible for her to go anywhere USC's can with out a visa? Sorry if this is confusing to you as well.

Except for Canada and Mexico she will still need a visa to enter countries that require visas from South African nationals.

THANK YOU!!!! That was all I was looking for Now for her to obtain a visa while in the US we just have to contact the South African Embassy in the US right?

If you are wanting to go to a foreign country for which she requires a visa you will have to contact that country's consulate or embassy. The South African embassy does not give out visas to other countries.